Quantitative assessment of chemical and mineralogical changes due to progressive low-temperature alteration of East Pacific Rise basalts from 0 to 9 Ma

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doi: 10.1016/j.chemgeo.2005.01.011
Authors:Schramm, Burkhard; Devey, C. W.; Gillis, K. M.; Lackschewitz, K. S.
Author Affiliations:Primary:
Universität Bremen, Fachbereich Geowissenschaften, Bremen, Federal Republic of Germany
IFM-GEOMAR, Federal Republic of Germany
University of Victoria, Canada
Volume Title:Chemical Geology
Source:Chemical Geology, 218(3-4), p.281-313. Publisher: Elsevier, Amsterdam, Netherlands. ISSN: 0009-2541
Publication Date:2005
Note:In English. Includes appendices. 82 refs.; illus., incl. 1 plate, 7 tables, sketch map
Summary:Many studies have focused on low-temperature alteration of the oceanic crust, nevertheless little is known about the initial processes of low-temperature alteration and their influence on the mineralogical and chemical composition of the oceanic crust once it leaves the spreading axis. The lack of such studies is primarily related to the difficulty of recovering samples representative of this initial alteration style. Such information is nevertheless important not only for crust-ocean mass-balances but also to characterize an important input to the subduction zones. We have studied dredged basalts from the eastern flank of the East Pacific Rise at 14°15'S, concentrating on the products of a single spreading segment in a corridor perpendicular to the spreading axis and covering a range of crustal ages from 0 to 9 Ma. Electron microprobe, X-ray fluorescence, X-ray diffraction and ICP-MS analyses have been carried out to examine the mineralogical and chemical changes in the basalts which make up the surface of the upper crust caused by low-temperature alteration. Fresh rocks were sampled at the ridge axis; off-axis basalts show features of progressive alteration. Celadonite is the main alteration component in 0.12-4.6 Ma old rocks, whereas phillipsite is more abundant in rocks older than 4.6 Ma. Changing compositions of secondary minerals, progressive sealing of fractures and the occurrence of more alteration rinds on older rocks show evidence for a slight change in redox conditions, from an oxidizing, water-dominated to a more reducing, rock-dominated environment with time. Iron oxyhydroxide and celadonite are the first alteration products, partly replaced or covered by saponite under more reducing conditions. The Fe necessary for the formation of these minerals is furnished by the dissolution of glass and the breakdown of olivine. Phillipsite is present in fractures and veins in rocks older than 1 Ma. Analyses also indicate an illite-smectite mixed layered mineral which is believed to be an intermediate between saponite and celadonite and small amounts of a chlorite/smectite mixed layered mineral. All samples are characterized by the lack of minerals formed by hydrothermal processes. We conclude that the alteration took place under seawater-dominated conditions at low temperature. A comparison of trace element analyses from altered whole rock samples and their appendant fresh glass chips provides a record of element mobility during alteration. Off-axis basalts show significant uptakes of Rb, Cs and Ba which are supplied by seawater and incorporated in or on secondary minerals. An enrichment of U is also apparent and appears to be especially strong when alteration conditions are oxidative. K2O is also gained in all altered off-axis basalts, believed to be linked to the formation of celadonite. However, the volume of rock being altered is so small relative to the volume of the oceans that this scavenging has no noticeable effect on the composition of the oceans. The composition of the oceanic crust, on the other hand, is affected significantly. Abstract Copyright (2005) Elsevier, B.V.
Sections:Clay minerals; Petrology
Subsections:Oceanic petrology
Subjects:Basalts; Cenozoic; Chemical composition; Clay minerals; Crust; Electron probe data; Fluid phase; Framework silicates; Geochemistry; Holocene; Hydrothermal alteration; ICP mass spectra; Igneous rocks; Low temperature; Major elements; Mass balance; Mass spectra; Metasomatism; Mineral assemblages; Mineral composition; Mobilization; Movement; Neogene; Nesosilicates; Oceanic crust; Olivine; Olivine group; Orthosilicates; Petrography; Phillipsite; Plate tectonics; Quantitative analysis; Quaternary; Saponite; Sea-floor spreading; Secondary minerals; Sheet silicates; Silicates; Spectra; Spreading centers; Temperature; Tertiary; Trace elements; Volcanic rocks; X-ray diffraction data; X-ray fluorescence spectra; Zeolite group; East Pacific; East Pacific Rise; Pacific Ocean
Coordinates:S160000 S140000 W1070000 W1130000
Abstract Numbers:07M/2908
Record ID:2005047807
Copyright Information:GeoRef, Copyright 2019 American Geosciences Institute. Reference includes data from CAPCAS, Elsevier Scientific Publishers, Amsterdam, Netherlands
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