The hydrochemical response of cave drip waters to sub-annual and inter-annual climate variability, Wombeyan Caves, SE Australia

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doi: 10.1016/j.chemgeo.2007.07.007
Authors:McDonald, Janece; Drysdale, Russell; Hill, David; Chisari, Robert; Wong, Henri
Author Affiliations:Primary:
University of Newcastle, School of Environmental and Life Sciences, Newcastle, N.S.W., Australia
ANSTO Environment, Australia
Volume Title:Chemical Geology
Source:Chemical Geology, 244(3-4), p.605-623. Publisher: Elsevier, Amsterdam, Netherlands. ISSN: 0009-2541
Publication Date:2007
Note:In English. 59 refs.; illus., incl. 4 tables, sketch maps
Summary:A thorough understanding of cave seepage waters is necessary to interpret geochemical variations in speleothem calcite in terms of changing surface climatic conditions at a particular site. Here we present the hydrochemistry of ten cave drip waters from a karst system in SE Australia based on up to 5.5 years of monitoring. Discharge was continuously measured at six sites and manually at the other sites. Dripwater samples were analysed for pH, electrical conductivity, cations and anions at all sites at monthly or more frequent intervals. Each drip possesses a unique chemistry, and not all drip waters responded to antecedent short-term hydrological variations. For example, the hydrochemical behaviour of three adjacent drips at a bedrock depth of 45 m was completely different to that of shallower sites, and was apparently unrelated to surface hydrology throughout the investigation. Based on modelled calcite precipitation vectors, prior calcite precipitation was demonstrated at several sites but can only be linked directly to changes in surface recharge at the shallowest sites. At extremely low flow, shallow drip waters accessed a high Mg, Sr and Ba source, thought to be the overlying soil. High-frequency sample collection allows for the calculation of predicted Mg/Cacalcite and Sr/Cacalcite values, highlighting that the sites with the greatest potential to record high-resolution palaeohydrological records are those situated at shallow depth. Longer temporal-resolution palaeohydrological records may be recorded at deeper sites but longer-term monitoring is required to identify probable time scales. Inherent system non-linearities, dissolution of secondary calcite in pore spaces of the aquifer, changes in the source of trace elements, and the presence of multiple reservoirs confirm the need for the use of multiple speleothems and a multi-proxy approach to gain accurate palaeohydrological records from this site. Abstract Copyright (2007) Elsevier, B.V.
Sections:Environmental studies; Geochemistry
Subjects:Alkaline earth metals; Annual variations; Barium; Bedrock; Calcite; Carbonate rocks; Carbonates; Caves; Chemical composition; Climate; Electrical conductivity; Geochemistry; Hydrochemistry; Hydrology; ICP mass spectra; Karst hydrology; Magnesium; Mass spectra; Metals; Paleoenvironment; PH; Precipitation; Sedimentary rocks; Soils; Solution features; Spectra; Speleothems; Strontium; Water balance; Australasia; Australia; New South Wales Australia; Taralga Australia; Wombeyan Caves
Coordinates:S341900 S341900 E1495900 E1495900
Abstract Numbers:07M/4266
Record ID:2008013767
Copyright Information:GeoRef, Copyright 2019 American Geosciences Institute. Reference includes data from CAPCAS, Elsevier Scientific Publishers, Amsterdam, Netherlands
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